The autothermal reformer in the sofcapu system is implemented with a. Simulation of doe demonstration systems city of las vegas clv refueling facility coproduces h 2 and electricity h 2 generator with steammethane reformer smr sized for 50 kw fuel cell with extra for vehicle refueling watervliet arsenal fuel cell demonstration 5kw fuel cell units with autothermal reformers. Simulation and optimization of propane autothermal. For the safe and troublefree operation of an autothermal reformer there is a need of knowledge about the interactions between the reactions and the fluid dynamic. Ive designed an autothermal reformer as part of a project and got a volume of around 200m3. Simulating and optimizing autothermal reforming of methane to. Modeling and simulation of catalytic partial oxidation in monolith reactors jorge emanuel pereira naalhov july 2, 20 abstract catalytic partial oxidation of hydrocarbons presents a promising route for synthesis gas and h 2 production for stationary decentralized and onboard applications. This paper presents a performance analysis for the autothermal reforming process of methane in a fixed bed reformer for hydrogen production. The developing software applications is executed with the support of the program packages dedicated to industrial processes and they will include acquisition and monitoring submodules, named virtually as well as the storage submodule of the process data later required for the software of optimization and simulation of the technological. D stationary reactor model describes the catalytic conversion of a gaseous hydrocarbon fuel with air and steam to synthesis gas by autothermal reforming and catalytic partial oxidation. In this paper, reformer autothermal reactor, which is the secondary reformer reactor in ammonia unit, has been modeled and simulated. The analysis is performed using aspen hysys software v8.
A codegeneratorbased software is presented which automatically. Software development for simulation of reformer furnace. The model employed the rksbm thermodynamic property package. For simulation of this reactor, combustion chamber flame area has. A dynamic process simulation model of the autothermal reformer and shift vessels was generated using aspen process simulation software. The hysys simulation software has been utilized for the simulations and calculations. Improve syngas production using autothermal reforming. Advanced modelling and optimisation of natural gas. This study presents the thermodynamic modelling of hydrogen production from autothermal reforming of synthetic crude glycerol using the pengrobinson stryjekvera thermodynamic model and gibbs free energy minimization approach. Comparison of startup and transient response with aspen. Analysis of hydrogen production from methane autothermal. Simulation and optimization of h2 production by autothermal. Analysis of integrated reformer fuel cell comparison to data from watervliet arsenal dod demonstration plug power 5kw units operated at 2.
Autothermal reforming of methane in a nimgal 2 o 4 catalyst reformer has been kinetically modeled. After the reformer, the syngas is cooled and cleansed of the particulates and inorganic impurities. Autothermal solutions has everything you need to get your production flow optimized. Autothermal reforming atr syngas generation air liquide. In this paper, a numerical research on dimethyl ether steam reforming reaction in a reactor has been presented using a computational fluid dynamics. The simulation results show that the dualbed autothermal.
Autothermal reforming atr syngas generation catalystbased syngas generation through partial oxidation and subsequent reforming of gaseous feed autothermal reforming atr is a process for producing syngas, composed of hydrogen and carbon monoxide, by partially oxidizing a hydrocarbon feed with oxygen and steam and subsequent catalytic. It aims to modify a complete mathematical model of the secondary reformer design. Other thesis, universiti teknologi malaysia, chemical engineering department. In this paper, autothermal reforming, for diesel onboard conversion into a hydrogenrich gas suitable for pem fuel cells, has investigated using the simulation tool aspen plus. The simulation had an autothermal reformer downstream of the gasifier. Thermodynamic analysis of autothermal reforming of synthetic. Autothermal reforming atr combines partial oxidation and steam reforming sr in a single process.
This paper presents the results of a study for a 100kw net electrical power pem fuel cell system. Transient simulation of an autothermal reformer, fuel. The reactions in the secondary reformer reactor are assumed to be carried inside two reactors in series. In autothermal reactor, after the feed gas and steam mixture is preheated, it is combusted with an oxidant and passed over a catalyst to bring the steammethane reforming reaction to equilibrium. The process flow data collected from the primary reformer survey are used in the developed. The catalytic reaction in the autothermal reformer takes place in one large vessel. In this research, fuel processor consists of an autothermal reactor, three water gas shift reactors and a. By using proper heat, mass, kinetic and thermodynamic models as well as effect of catalyst shape, the software has been developed for the reformer furnace simulation for syngas and hydrogen production. An onboard autothermal reformer atr employed to reform the desulfurized jp8 fuel was coupled with the psofc stack to provide for h 2 and co as.
The ammonia production plant starting from the gasifier was modelled in aspen plus software. In this work, a performance of the dualbed autothermal reforming of methane for hydrogen production is analyzed. Autothermal reactor interactive simulation youtube. Advanced modelling and optimisation of natural gas reforming. To be confident of feed conversion 1700 k temperature is needed. The results of the simulation of an industrial steam reformer are also discussed. Numerical simulation of methane partial oxidation in the. Autothermal reforming atr, that is the combination of noncatalytic partial oxidation and adiabatic steam reforming, is an important process to produce synthesis gas syngas from natural gas. Thermal simulation software in the cloud simscale you can create a free account and perform the needed. In this work, synthesis gas production by autothermal reforming was. This study presents the thermodynamic modelling of. The operation conditions of the auto thermal reformer have been studied in detail to determine the values, which lead to the production of a hydrogen rich gas mixture with co concentration at ppm level.
The major system components are an autothermal reformer, high and low temperature shift reactors, a preferential oxidation reactor, a pem fuel cell, a combustor and an expander. Steam srm and autothermal atr reforming of methane processes were evaluated through thermodynamical and stoichiometric analyses that benefit hydrogen production, using. Modern techniques for optimization of primary reformer. Investigation of a dualbed autothermal reforming of. Modeling and simulation of an industrial secondary reformer. Onboard diesel autothermal reforming for pem fuel cells. Jul 19, 2012 in this paper, the industrial secondary reformer reactor has been modeled and simulated at steadystate operation conditions. Ravi kumar mandela houston, texas area professional.
The first section of ptal2o3 catalyst is designed for oxidation reaction, whereas the second one based on nimgal2o4 catalyst involves steam reforming reaction. Equilibrium composition out of a steam reformer at 26 bar with a feed steam to methane ratio of 2. Pdf investigation of an integrated autothermal reforming atr. Optimization of a methane autothermal reformingbas ed hydrogen production system with low co 2 emissions wei wu,a and chutima tungpanututh b adepartment of chemical engineering, national cheng kung university, tainan 70101, taiwan, r.
Jun 18, 2015 an animation of tris tris proprietary steam reformer gasification system. In order to simulate the typical crude glycerol, a solution was prepared by mixing glycerol, methanol, soap, and fatty acids. Using a commercial dynamic flow sheeting software, hysys 3. In this work, standalone autothermal reforming systems using methanol is evaluated according to hydrogen yield, cost of hydrogen production and energy consumption. Reform3pc steamhydrocarbon reformers simulation program. Autothermal reformer cost posted in industrial professionals. The job of the reformer is to reform the methane and tars in the incoming syngas. To simulate the flow regime, the researchers used the k. This paper presents a performance analysis of a dualbed autothermal reformer for hydrogen production from methane using a nonisothermal, one dimensional reactor model. Modeling of autothermal reforming of methane in a fluidized bed reactor with.
The steam methane reformer uses an external source of hot gas to heat tubes containing a mixture of steam and methane. Synthesis gases produced by smr from natural gas have h 2 co ratios between 2. Hysys software to investigate the effect of major operating parameters on the reformer performance. The well known cfd commercial software, fluent 6 was used for modeling. A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst.
Modeling and dynamics of an autothermal jp5 fuel reformer for marine fuel cell applications, energy, elsevier, vol. Independent parameters that affect the performance of an atr reactor are. Computational fluid dynamics simulation of steam reforming and. Determine catalyst performance h2 yield, cox selectivity, hydrocarbon breakthrough, fuel conversion. So far there is no research about 3d simulation of autothermal reformer by. The process simulation package aspenhysys has been used along with conventional calculations. To answer technological questions about the reactors operating response a model was developed that allows the simulation of different consecutive states like load changes and start up procedures. Fbcr was used for detailed modelling of the catalyst beds considering rigorous intraparticle mass and heat transport. Simulation of doe demonstration systems city of las vegas clv refueling facility coproduces h 2 and electricity h 2 generator with steammethane reformer smr sized for 50 kw fuel cell with extra for vehicle refueling watervliet arsenal fuel cell demonstration. Investigation of an integrated autothermal reforming atr and. For kinetic modeling, reformer were divided in two sections, upper noncatalytic partial oxidation and lower catalytic steam reforming. In this paper, reformer auto thermal reactor, which is the secondary reformer reactor in ammonia unit, has been modeled and simulated. Gasification is a thermochemical process that converts any carboncontaining material into a synthesis gas syngas.
Fluent fluid flow simulation software from ansys to analyze the flow in the reformer mixing chamber. Work has been completed for the following flow sheets. A threedimensional reactor model developed by the commercial software comsol version 5. The model defines two subsequent sections in the reactor. Feb 26, 2018 autothermal reformer cost posted in industrial professionals.
Simulation and optimization of h2 production by autothermal reforming of. Aspenhysys simulation of methanol to dimethylether dme. Design and control of standalone autothermal reforming. When compared to the thermodynamic equilibrium simulation based on adiabatic condition. Describes how to use an interactive simulation that solves the differential equations for an autothermal reactor, which is a catalytic reactor in which the feed gas is preheated in an annular. Modeling and simulation of catalytic partial oxidation in. Feb 25, 2015 describes how to use an interactive simulation that solves the differential equations for an autothermal reactor, which is a catalytic reactor in which the feed gas is preheated in an annular.
Thermodynamic analysis of autothermal reforming of. Numerical simulation of methane partial oxidation in the burner and. Jan 01, 2004 the autothermal reformer burns a portion of the natural gas within the reforming vessel to provide heat for the reaction. Jul 01, 2008 read transient simulation of an autothermal reformer, fuel processing technology on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Steam srm and autothermal atr reforming of methane processes were evaluated through thermodynamical and stoichiometric analyses that benefit hydrogen production, using a nigal 2 o 3 catalyst. The gproms advanced model library for fixedbed reactors aml.
It is located after the primary reformer in the ammonia plant where it is used in the synthesis of ammonia. However, the crude glycerol in their study was modelled as a mixture of glycerol and methanol only, and the presence of other impurities present in crude glycerol was not taken into consideration. Simulation and optimization of ethanol autothermal reformer for fuel cell applications muhamad syafiq bin adam a report submitted in partial fulfilment of the requirements for the award of the degree of bachelor of engineering chemical faculty of chemical engineering and natural resources engineering universiti teknologi malaysia november 2006. Reform3pc steam hydrocarbon reforming simulation program. Simulation study of a proton exchange membrane pem fuel. The secondary reformer is a part of a subprocess in a higher scale unit of ammonia synthesis. Autothermal reformer cost industrial professionals. An animation of tris tris proprietary steam reformer gasification system. Hydrogen fuel cell is one promising solution, but the nature of the gas is such that the invehicle conversion of other fuels into hydrogen is necessary. Optimization of a methane autothermal reformingbased. Modeling and simulation of an industrial secondary. It simulates most reforming furnace types such as up, down, or side fired rectangular and cylindrical types, as well as terrace wall. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane. Read transient simulation of an autothermal reformer, fuel processing technology on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips.
Twosection reactor model for autothermal reforming of methane to. For methane as fuel, simulation results are presented and compared. The job of the reformer is to reform the methane and tars in the incoming. The model was solved using a software package femlab 3. Based on the type of nozzle in the reformer, they chose to use the pressure swirl atomizer model. Autothermal reforming of natural gas to synthesis gas. Have a look at this cloudbased thermal simulation platform. Can anyone give any idea of how much this piece of equipment normally costs. Modeling of autothermal reforming of methane in a fluidized bed. Autothermal reforming as a hydrocarbon fuel processing option for.
Provided support to develop pilot plant for the conversion of natural gas to methanol developed and tested process simulation models using aspen plus software autothermal reformer, amine unit. Comparison of startup and transient response with aspen model. Parameter analysis and numerical simulation of hydrogen. Modeling and analysis of autothermal reforming of methane to.
It is located after the primary reformer in the ammonia plant where it is used in the. Reform3pc is a rating program for the firebox sections of steammethane reformer furnaces, which are used in hydrogen, ammonia and oxoalcohol production. In this paper, the industrial secondary reformer reactor has been modeled and simulated at steadystate operation conditions. The autothermal reformer burns a portion of the natural gas within the reforming vessel to provide heat for the reaction.
Hydrogen h 2 production is gaining popularity among researchers for a better future environment. The secondary reformer reactor is located after the primary one and consists of a combustion chamber and a catalytic bed. The system design includes several features that enhance system response and serve to reduce startup time. Autothermal reformer an overview sciencedirect topics. The simulation of the experimental reactor during the optimization of the tortuosity factor also yielded the effectiveness factors of the reactions. A nonisothermal, onedimensional reactor model is used to investigate the reformer performance in terms of methane conversion and h2co product ratio. Simulation and optimization of propane autothermal reformer for fuel cell applications insiong, henry 2006 simulation and optimization of propane autothermal reformer for fuel cell applications. Modeling and dynamics of an autothermal jp5 fuel reformer for. Steam hydrocarbon reforming simulation program reform3pc is a rating program for the firebox sections of steammethane reformer furnaces, which are used in hydrogen, ammonia and oxoalcohol production. A steady state planar solid oxide fuel cell psofc based system operating on desulfurized jp8 fuel was modeled using aspen plus simulation software for auxiliary and mobile power applications. The effects of h2och4 feed ratio, o2ch4 feed ratio and.
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